In accordance with ISO 80000-2, the following font conventions are employed:
Scalars and components for vectors or tensors are represented by lightface italic type ().
Vectors are represented by boldface italic type ().
Second-order tensors are represented by boldface sans-serif type ().
Operators & Constants: Roman (upright) type is used for fixed mathematical constants (e.g., Pi , the imaginary unit ) and differential operators (e.g., the differential in ).
Calculus Notation: For integrals, a thin space (\,) is used to separate the integrand from the differential operator, e.g., .
Minkowski Metric: The Minkowski metric tensor is defined using the mostly-plus signature convention:
Consequently, the invariant spacetime interval is given by .
Lorentz transformation
For -axis boost (where moves with velocity relative to ), the transformation matrix is:
1 Static Electric Field
1.1 Multipole expansion
Consider electrostatic potential expansion at an external observation point , with localized charge source confined within a volume , and , then
Where is total charge, is electric dipole moment, is electric quadrupole moment.
Electrostatic intensity expansion
1.2 Small charged body in electric field
Assuming the charge of charged bodies is so small compared with the source which generates the electric field that . Let be the relative coordinate of a charge element from the body's center . The potential energy of the small body is,
Note that , , are intrinsic properties of the small charged body itself, not the external source.
Furthermore, The total electrostatic force acting on the small charged body is,
The total force moment acting on the small charged body about its center is,
1.3 Spherical harmonic expansion
1.3.1 Orthonormal Complete Set of Functions
Definition
Orthonormality
Completeness: Any square-integrable function can be expanded as
which implies
Trigonometric & Complex Exponential Functions
Note: for sine set; for cosine set; for complex set.
Legendre Polynomials
Spherical Harmonics
For negative , the relations are given by:
The first few associated Legendre functions are,
Orthonormality
Completeness
1.3.2 Multipole expansion *
By using the Legendre generating function, one finds
Consider a localized charge distribution confined within a volume . The exact electrostatic potential at an external observation point (where , hence and ) is given by,
Monopole Term (Point Charge). For , since , the first term simplifies to:
Dipole Term. For , since , the second term becomes:
Quadrupole Term. For , since , substituting into the expression yields:
And extending to yields the octupole (), hexadecapole (), and more high -pole moments
1.3.3 Wigner -Matrices *
Spherical harmonics form a -dimensional irreducible representation of . Under a coordinate rotation parameterized by the Euler angles , the total angular momentum quantum number remains invariant because the rotation operator commutes with the total angular momentum squared: . However, the azimuthal projection undergoes a linear transformation.
The transformed spherical harmonic in the rotated frame can be expressed as a linear combination of the original basis functions,
where are the elements of the Wigner -matrix. We find that the entire rotation operator can be directly written as . Thus, Wigner -matrix can be factorized into a product of exponentials and Wigner's small -matrix,
Here, Wigner's small -matrix describes the rotation around the -axis,
Since spatial rotations preserve the norm of the state space, the Wigner -matrix is strictly unitary, satisfying,
Specially, when the second projection index is set to zero (), the Wigner -matrix simplifies directly to a spherical harmonic,
You can computes the Wigner -matrix and small -matrix elements analytically by using the built-in WignerD function with the following syntax in Wolfram Mathematica (MMA),